Saturday, May 16, 2009

In chemistry and physicsDalton's law (also called Dalton's law of partial pressures) states that the total pressure exerted by a gaseousmixture is equal to the sum of the partial pressures of each individual component in a gas mixture. This empirical law was observed by John Dalton in 1801 and is related to the ideal gas laws.

Mathematically, the pressure of a mixture of gases can be defined as the summation

P_{total} = \sum_{i=1} ^ n {p_i}       or      P_{total} = p_1 +p_2 + \cdots + p_n

where p_{1},\ p_{2},\ p_{n} represent the partial pressure of each component.

It is assumed that the gases do not react with each other.

\ P_{i} =P_{total}x_i

where x_i\ =  the mole fraction of the i-th component in the total mixture of m components .

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