There are many ways of stating the second law of thermodynamics, but all are equivalent in the sense that each form of the second law logically implies every other form.[1] Thus, the theorems of thermodynamics can be proved using any form of the second law and third law.
The formulation of the second law that refers to entropy directly is as follows:
In a system, a process that occurs will tend to increase the total entropy of the universe.
Thus, while a system can undergo some physical process that decreases its own entropy, the entropy of the universe (which includes the system and its surroundings) must increase overall. (An exception to this rule is a reversible or "isentropic" process, such as frictionless adiabatic compression.) Processes that decrease total entropy of the universe are impossible. If a system is at equilibrium, by definition no spontaneous processes occur, and therefore the system is at maximum entropy.
No comments:
Post a Comment